Regulations (物性及检验规范) Thursday 17/10/2013

1.Light Fastness

Determined according to CEI 02-59: “Light Fastness” by exposure of prints to daylight and to the xenon lamp. Assessment is recorded in comparison with the ISO Blue Scale for textiles. Rating 8 denotes the best, 1 the poorest degree of fastness.

2.Acid Resistance

Dipping printed sample in 5% hydrochloride solution at room temperature for 30 min. Assessment is determined according to the fading conditions of the test samples. It can be divided into five grades.
Grade 1
Complete fading.

Grade 2Fair fading.

Grade 3Fading.

Grade 4Slight fading.

Grade 5No fading at all.

3.Alkali Resistance

Dipping printed samples in 2% caustic alkali solution at room temperature for 30 min. The assessment is determined in the same way as Acid Resistance.

4.Migration

Placing the test sample between two pieces of 40 phr PVC sheets and then clipping the test set by two pieces of glasses (5cm square). The test set is pressed by 5kg iron and then placed into the oven at 80 for 24 hours.

No migration phenomenon.

With significant migration phenomenon.

5.Heavy Metal Content

According to the test method of EN-71, part 3:1994 standard. The sample is dipped into 0.07N HCl aqueous solution and vibrated at 37 for one hour. The filtrate is then analyzed by ICP (Induced Coupling Plasma). The controlled limited is shown as below:

Heavy Metal

Pb

Sb

As

Ba

Cd

Cr

Hg

Se

mg/kg

<90

<60

<25

<1000

<75

<60

<60

<500

Has passed the entire requirement of EN-71 standard.

Could not pass the entire requirement of EN-71 standard.

6.Analysis of Azo Dye

According to German Bedarfsgegenstande-Verordnung test method. The sample is digested in aqueous solution of sodium sulfite at 70with citric acid buffer solution of pH 6. Then extracted with tert-butyl methyl ether and detected by GC-MS.

Under the controlled limit.

Higher than the controlled limit.

7.Formalin Test

According to the standard of DIN 53315, the sample is dipped into pure water and vibrated at 40 for one hour. The filtrate is then analyzed by HPLC with acetonitrile as eluent.

Under the controlled limit.

Higher than the controlled limit.



1. 耐旋光性

依据BS-1006标准方法测试,共分1~8级,1级最差,8级最佳。

2. 耐酸性

于室温下将油墨试片浸泡于5%盐酸水溶液中,经过30分钟后取出观察油墨试片变色及浸泡液着色的程度,其结果分下列五种情况:
5级:油墨试片无变色,且浸泡液亦无着色。

4级:油墨试片轻微变色,浸泡液亦轻微着色。

3级:油墨试片明显变色,浸泡液亦明显着色。

2级:油墨试片严重变色,浸泡液亦严重着色。

1级:油墨试片完全变色。

3. 耐碱性

于室温下将油墨试片浸泡于2%氢氧化钠水溶液中,经过30分钟后取出观察油墨试片变色及浸泡液着色的程度,其判定方式同耐酸性判定标准。

4. 渗透性

将油墨试片与PVC白皮(DOP含量为40phr)利用5x5cm2之玻璃片夹在一起,以5kg铁块重压后放置于50之烘箱中,24小时后取出观察是否有颜色渗透到PVC白皮上。

:白皮无渗透。

:白皮有渗透。

5. 含铅量

依据N-71 Part 3: 1994八大重金属检验标准,将样品置于0.07NHCl溶液中,在37下震荡一小时后过滤,再以电浆偶合诱导元素分析仪检测之,其管制标准如下:

元素

(Pb)

(Sb)

(As)

(Ba)

(Cd)

(Cr)

(Hg)

(Se)

mg/kg

90以下

60以下

25以下

1000以下

75以下

60以下

60以下

500以下

:各重金属含量低于EN-71八大重金属检验标准。

:重金属含量超出EN-71八大重金属检验标准。

6. 偶氮测试

依照德国Bedarfsgegenstande-Verordnung 之测试标准,将样品置于亚硫酸钠之70PH 6的柠檬酸缓冲溶液中,以甲基四丁基醚萃取后,再以气相层析质谱仪分析之。

:通过检验标准。

:未通过检验标准。

7. 福尔马林测试

依照DIN53315之检测标准,将样品置于纯水中,在40下震荡一小时后过滤后,以acetonitrile当流动相,以高效能液相层析仪(HPLC)检测之。

:通过检验标准。

:未通过检验标准。